MSIS spray chamber

Hello everyone, 

I have a problem dropping unstability intensity used MSIS spraychamber to determination mercury. 

I used NaBH4 as reductant 

I didnt use pre reductant as example L-cystine or tartaric

I started run standard Hg 50ppb  have good intensity, i run calibration then i try 10 sampel CRM have good recovery but after 5 sample, i saw dropping intensity.  I checked standard concentration Hg 50ppb run as sample the intensity and concentration was dropping too. 

I recalibrate standard calibration and run CRM again,  recovery back to normal but after 4 sample, i saw dropping intensity again. 

Any sugestion about this? 

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