Compounds quantitating at zero instead of expected concentrations - MH Quant 10.2 in Environmental mode

I run EPA method 624.1 and have been working through the MDL procedure for this method and have found that a few compounds are consistently quantitating at or approaching 0.000 ppb when a 0.5 ppb injection is used (this is the lowest point on the curve and that which I normally use to calculate MDL's).  For example, bromomethane seen below, the target peak area count in this sample is more than the area count for 0.5 ppb in the iCAL file, yet it is still quantitating at zero.  Any help is appreciated.  Thank You.  

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