High ratio of mass 70 to mass 69 and high mass 69 precursor

When I run tune evaluation it reports that mass 70 to mass 69 is high, as well as the mass 69 precursor, should I be overly concerned?  If so how do I fix it?  I'm also questioning the background/stability and I'm wondering if there is a leak or leaks.  I attached the auto tune, tune evaluation and air/water check reports.  When I compare recent injections of the a standard to the same injections of this standard from around 6-7 months ago the TIC baseline noise seems worse and the quality of peaks is not as good; the peaks are much smaller and not as well defined.  Is this possibly due to bad background because of a leak or something else?

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