In Intelligent Report you can show your results using the table Compound Summary, but I need to order the tables by the retention time, and not by alphabetical order as it is shown in the image below.
This can be changed in the table's Peaks and Repeating properties. To access these you need to right-click on the compound summary table in the report editor and select 'Properties' from the right-click action menu. When you select Peaks and Repeating on the left of the Properties window you should see something like the below image:
The default field to repeat the table on is Compound_Name which is what you are seeing on your report. In your case you would want to instead repeat the table on Compound_ExpectedRetTime.
Hopefully that helps.
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