For environmental analysis of POP's with QQQ, we aquire at least two transitions.
The first one to quantitate, the latter ones as qualifiers whitch should lie between ± 20% of the expected ion ratio.
However, for very small peaks ( < 2 times LOQ) it is allowed to elevate this threshold to ± 50% and it is up to the analyst to evaluate and approve it.
First: Is there a way to incorporate this "flexible" threshold into the quantification method software? I can only find the way to evaluate ion ratio outliers (Method tasks -> Outlier Setup tasks -> Qualifier ratio) but this is very rigid.
Second: Is there a way for the analyst to approve an outlier in such a way that the flag is removed (or overruled) but still is registrated by the CDS?