MassHunter Arrange Compounds By/User Defined

In MassHunter, how do you utilize the Arrange Compounds By/User Defined capability? I would like to be able to group my compounds by compound class, so that I report surrogates as a group, and families of compounds as different groups, rather than by retention time or alphabetically order etc. I would especially like a way to do this for report generation. Is the Arrange Compounds By function helpful here?

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