Analysis of Polycyclic Aromatic Hydrocarbons in Petroleum Vacuum Residues by Multiple Heart-Cutting LC Using the Agilent 1290 Infinity 2D-LC Solution

Version 1

    Application Note

    Energy and Chemicals

     

    Abstract

    Polycyclic aromatic hydrocarbons (PAHs) were determined in a petroleum vacuum distillation residue using the Agilent Multiple Heart-Cutting (MHC) 2D-LC solution. The extract was analyzed in the first dimension by normal-phase LC. Well-defined fractions from this separation were stored in a set of sample loops, then transferred online to the second-dimension separation where the PAHs were separated from each other and from other sample constituents using reversed-phase LC on a dedicated PAH column. Detection was performed with diode-array detection (DAD) as the monitor detector after the first dimension, and with fluorescence detection (FLD) after the second dimension. An additional column switching valve enabled backflush of the first-dimension normal-phase column to remove highly polar components. The Agilent 1290 Infinity 2D-LC solution enabled automated, selective, and quantitative analysis of the PAHs in the complex petroleum vacuum distillation residue sample.

     

    Publication number: 5991-6549EN

    Publication Date: February 1, 2016

     

    http://www.agilent.com/cs/library/applications/5991-6549EN.pdf